If you purchased the Digital Deluxe Edition, there are some suits and other items you can claim. This guide on Where To Find Digital Deluxe Edition Pre-Order DLC In Marvel’s Spider-Man 2 will tell you where to find each of the different items that come with the special upgrade.
Some of these items are unlocked at different parts of the starting section of the game. Once you have progressed far enough to unlock the Skills menu, found on the main menu, you will get the free additional skill points that come with the Digital Deluxe Edition. If you want to get the new suits, you need to progress a little further.
Where To Find Digital Deluxe Edition Pre-Order DLC In Marvel’s Spider-Man 2
You unlock the suits as you follow the main story. You will get a mission where Peter says he wants to change clothes because his current suit is full of sand. This will take you to a nearby rooftop where you will open a bag and grab a new suit. This unlocks the Suit menu on the main menu. You can then navigate to the very bottom of the menu to find the suits that come with the Digital Deluxe Edition DLC